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ChemInform Abstract: tert-Butyl Hypofluorite — An Electrophilic tert-Butoxylation Agent.

✍ Scribed by I. BEN-DAVID; E. MISHANI; S. ROZEN

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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The tert-Butyl Sulfoximine Group as an Effective ortho-Director of Lithiation: ortho-Metalated S-(tert-Butyl)-S-phenylsulfoximines. -Lithiation of the S-tert-butyl-S-phenylsulfoximines (I) occurs selectively at the ortho-position. Trapping with electrophiles at -78 • C affords the orthosubstituted