✦ LIBER ✦
ChemInform Abstract: Terminal Ligand Assignments Based on Trends in Metal—Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters.
✍ Scribed by B. M. SEGAL; H. R. HOVEYDA; R. H. HOLM
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
✦ Synopsis
Terminal Ligand Assignments Based on Trends in Metal-Ligand Bond Lengths of Cubane-Type [Fe 4 S 4 ] 2+,+ Clusters. -Single crystal XRD analysis shows, that the compound (IV) crystallizes in the tetragonal space group P42 1 c (Z = 2). Furthermore, the compound (Pr 4 N) 2 [Fe 4 S 4 Cl 4 ] is obtained in 85% yield from (Pr 4 N) 2 [Fe 4 S 4 (SH) 4 ] and 1,2-dichloroethane (room temperature, 15 min). -(SEGAL, B.