✦ LIBER ✦
ChemInform Abstract: Tandem Reaction of Ethyl α-(Per(poly)fluoroalkyl)acetates with Allylic Alcohols: A Convenient Synthesis of Ethyl α-(2-Alkenyl)-. alpha.-(per(poly)fluoroacyl)acetates.
✍ Scribed by B.-H. LUO; H.-P. GUAN; C.-M. HU
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1997 carboxylic acid esters carboxylic acid esters (acyclic compounds) P 0360 45 -085 Tandem Reaction of Ethyl α-(Per(poly)fluoroalkyl)acetates with Allylic Alcohols: A Convenient Synthesis of Ethyl α-(2-Alkenyl)-. alpha.-(per(poly)fluoroacyl)acetates.
-An efficient synthesis of the title compounds of type (III) and (V) is presented, which starts with readily available reagents and affords high yields. The tandem reaction includes dehydrofluorinations and Claisen rearrangement of the allyloxy derivatives. -