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ChemInform Abstract: Tandem Organolithium Addition/Oxa-Bridge Opening of 8-Oxa[3.2.1]bicyclic Pyrone—Alkene Adducts.

✍ Scribed by J. Ramon Rodriguez; Luis Castedo; Jose L. Mascarenas


Publisher
John Wiley and Sons
Year
2000
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ A. TAKO; K.-H. ONGANIA; K. WURST 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

Heterocyclically Bridged Tricyclic β-Lactames: A Simple Synthesis of 1,2,2a,8a-Tetrahydro-3-oxa-1-aza-cyclobuta[b]naphthalen-2-ones. -The novel title heterocycles such as (VI) and (VII) are obtained via 6-exo-trig radical cyclization. The structure of compound (VIIb) is confirmed by X-ray analysis.