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ChemInform Abstract: Tandem One-Pot Synthesis of α-(Aminomethylene)-γ-butyrolactones via Regioselective Epoxide Ring-Opening with the Blaise Reaction Intermediate.

✍ Scribed by Young Ok Ko; Yu Sung Chun; Youngmee Kim; Sung Jin Kim; Hyunik Shin; Sang-gi Lee

Publisher: John Wiley and Sons
Year: 2011
Weight: 37 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201113077

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✦ Synopsis

Abstract

The reaction of the Reformatsky reagent derived from ethyl bromoacetate and subsequent coupling of the resulting Blaise intermediate with oxiranes allows the synthesis of the title compounds in fair yields.

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