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ChemInform Abstract: Taming the Silylium Ion for Low-Temperature Diels—Alder Reactions.

✍ Scribed by Hendrik F. T. Klare; Klaus Bergander; Martin Oestreich

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
41
Category
Article
ISSN
0931-7597

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Catalytic Asymmetric Diels-Alder Reactions of α-Thioacrylates for the Preparation of Norbornenone. -Cu(II)-catalyzed asymmetric Diels-Alder cycloaddition of α-thioacrylates (I) with excess cyclopentadiene using a bisoxazoline as chiral auxiliary provides the corresponding cycloadducts (III) in high