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ChemInform Abstract: Ta5Se1.2Te1.8 - A Tetrahedrally Close-Packed Metal-Rich Layer Structure.

✍ Scribed by M. CONRAD; B. HARBRECHT


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


1997 structure structure (solids and liquids) D 2000

29 -008

Ta5Se1.2Te1.8 -A Tetrahedrally Close-Packed Metal-Rich Layer Structure. -The novel title compound is synthesized by reaction of TaSe2 and TaTe2 with Ta at 1540 β€’ C and characterized by single-crystal XRD. The structure (triclinic, P1, Z = 8) adopts a novel structure type which consists of heteronuclear, distorted icosahedral clusters which form pentagonal antiprismatic columns. Connection of these columns by Ta-Ta and Ta-Te/Se contacts yields tetrahedrally close-packed layers.


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ChemInform Abstract: Original Close-Pack
✍ Artem M. Abakumov; Joke Hadermann; Alexander A. Tsirlin; Haiyan Tan; Jo Verbeeck πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons βš– 16 KB

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