ChemInform Abstract: Synthetic Study of Pinnatoxin A: Intramolecular Alkylation Approach to the G-Ring.
β Scribed by Aiko Nitta; Akihiro Ishiwata; Takeshi Noda; Masahiro Hirama
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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The functionalized tricyclic framework (XI) of the diterpene forskolin is synthesized by an intramolecular Diels-Alder reaction of the dienyne (VII), which is obtained by stereoselective introduction of the C side chains at C-1 and C-2 of tri-O-acetyl-D-galactal (I) via C-Ferrier and Claisen-Ireland