𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Synthetic Studies Towards Novel Tetracyclic Lycopodium Alkaloids: A Synthesis of Deoxymagellaninone.

✍ Scribed by G. MEHTA; M. S. REDDY; A. THOMAS

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
29
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Synthetic Studies Towards Novel Tetracyclic Lycopodium Alkaloids:

A Synthesis of Deoxymagellaninone.

-A novel, linear triquinanebased strategy directed towards the synthesis of tetracyclic alkaloids of the paniculatine and magellanine type is presented and applied to the preparation of deoxymagellaninone (XVII). The synthesis involves the 'carbocycle-heterocycle equivalency' strategy for the introduction of the N-methylpiperidine ring (D) from a cyclopentene precursor. Construction of the cyclohexane ring (A) with the correct stereochemistry is achieved via butenylation of linear triquinane (IV) and intramolecular Michael addition of the derived methylcarbonyl compound (VIII) or alternatively, a cationic enone-olefin cyclization. -(MEHTA, G.;

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Model Studies Towar
ChemInform Abstract: Model Studies Toward the Total Synthesis of the Lycopodium Alkaloid Spirolucidine (II).
✍ Daniel L. Comins; Alfred L. Williams πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

ChemInform Abstract: Synthetic Studies T
ChemInform Abstract: Synthetic Studies Toward Diazonamide A. A Novel Approach for Polyoxazole Synthesis.
✍ Peter Wipf; Joey-Lee Methot πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

ChemInform Abstract: Synthetic Approach
ChemInform Abstract: Synthetic Approach Towards Nakadomarin A: Efficient Synthesis of the Central Tetracyclic Core.
✍ Toshiaki Nagata; Atsushi Nishida; Masako Nakagawa πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 27 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v