Application of the 2-Azaallyl Anion Cycloaddition Method to an Enantioselective Total Synthesis of (+)-Coccinine. -The nonnatural enantiomer (XI) of the alkaloid (-)-coccinine is enantioselectively synthesized with cycloaddition of (VII) to (VIII) as the key step. -(PEARSON, W. H.;
ChemInform Abstract: Synthetic Studies on Lepadiformine Using the 2-Azaallyl Anion Method.
β Scribed by William H. Pearson; Yi Ren
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Synthetic Studies on the Erythrina Alkaloids. Preparation of (Β±)-2-epi-Erythrinitol. -The synthetic route to the racemic title alkaloid (IX) features a [1 + 4] vinyl isocyanate (I)-isocyanide (II) cycloaddition and an intramolecular Heck reaction of the iodide (VII) as key steps. -(RIGBY,
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