ChemInform Abstract: Synthetic Potentialities of Sulfonylsulfonium Salts: A New Approach to the Preparation of Disulfonium Dications.
β Scribed by N. E. Shevchenko; V. G. Nenaidenko; E. S. Balenkova
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 28 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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A Novel Synthetic Approach to the Preparation of Various Ξ±,. alpha.-Difluoroesters. -Successive condensation of ethyl bromofluoroacetate with thiophenol and aldehydes provides Ξ±-fluoro-Ξ²-hydroxy-Ξ±-phenylthio esters (I). Treatment of these esters with exception of (Id) with DAST yields rearranged Ξ±,