ChemInform Abstract: Synthetic Oligonucleotides as RNA Mimetics: 2′-Modified RNAs and N3′→P5′ Phosphoramidates
✍ Scribed by M. Egli; S. M. Gryaznov
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 27 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Cycloaddition/Ring Opening of 3-Unsubstituted Cyclic Nitronates, Isoxazoline and 5,6-Dihydro-4H-1,2-oxazine N-Oxides, as Synthetic Equivalents of Functionalized Nitrile Oxides. -Treatment of 3-halo-1-nitropropane [cf. (I)] with base results in cyclization to a nitronate. Trapping with electron-rich