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ChemInform Abstract: Synthesis, Structure, and Ring Inversion of a Trithiolane (6b, 12b-Epitrithioacenaphtho[1,2-a]acenaphthylene).

✍ Scribed by Yoshiaki Sugihara; Koichi Abe; Juzo Nakayama

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Synthesis, structure, and ring inversion
Synthesis, structure, and ring inversion of a trithiolane (6b,12b-epitrithioacenaphtho[1,2-a]acenaphthylene)
✍ Yoshiaki Sugihara; Koichi Abe; Juzo Nakayama πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 229 KB

Reduction of 6b, acenaphthylene 2, prepared by sulfuration of acenaphtho [1,2-a]acenaphthylene 1, with LiEt 3 BH, followed by air-oxidation, resulted in the desulfuration that led to 6b,12b-epitrithioacenaphtho[1,2-a]acenaphthylene 7 in 87% yield. The trithiolane ring of 7 adopts an envelope confor