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ChemInform Abstract: Synthesis, Resolution, and Crystallographic Characterization of a New C2-Symmetric Planar-Chiral Bipyridine Ligand: Application to the Catalytic Enantioselective Cyclopropanation of Olefins.

✍ Scribed by Ramon Rios; Jack Liang; Michael M.-C. Lo; Gregory C. Fu


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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Design, Synthesis, and Application of a C 2 Symmetric Chiral Ligand for Enantioselective Conjugate Addition of Organolithium to Ξ±,Ξ²-Unsaturated Aldimine. -Acyclic aldimines (I), cyclic aldimines (IV), and naphthaldehyde imines like (VI) undergo enantioselective conjugate additions to organolithiums