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ChemInform Abstract: Synthesis of ω-Nitro Acids and ω-Amino Acids by Ring Cleavage of α-Nitrocycloalkanones.

✍ Scribed by Roberto Ballini; Fabrizio Papa; Corrado Abate

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthesis of ω-Nitro Acids and ω-Amino A
Synthesis of ω-Nitro Acids and ω-Amino Acids by Ring Cleavage of α-Nitrocycloalkanones
✍ Roberto Ballini; Fabrizio Papa; Corrado Abate 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB

Water / α-Nitrocycloalkanones / ω-Nitro acids / Surfactant The reaction of various α-nitrocycloalkanones 1 with of the latter with HCOONH 4 /Pd-C, in methanol, at 80 °C affords ω-amino acids 3. The synthesis of methyl 9-aqueous 0.05 M NaOH, at 80 °C, in the presence of cetyltrimethylammonium chlori