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ChemInform Abstract: Synthesis of α,β-Disubstituted Ferrocenes via a Ferrocenylepoxide Intermediate. Preparation and Catalytic Activity of a New Chiral Ferrocenyloxazoline.

✍ Scribed by Angela Patti; Matthias Lotz; Paul Knochel

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Catalytic Enantiose
ChemInform Abstract: Catalytic Enantioselective Construction of β-Quaternary Carbons via a Conjugate Addition of Cyanide to β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds.
✍ Yuta Tanaka; Motomu Kanai; Masakatsu Shibasaki 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 46 KB

## Abstract A general catalytic enantioselective conjugate addition of cyanide to β,β‐disubstituted α,β‐unsaturated ketones and N‐acylpyrroles is developed using a strontium catalyst derived from Sr(OiPr)~2~ and a new chiral ligand.