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ChemInform Abstract: Synthesis of (Z)-Organylthioenynes Using KF/Al2O3/Solvent as Recyclable System.

✍ Scribed by Diego Alves; Maraisa Sachini; Raquel G. Jacob; Eder J. Lenardao; Maria E. Contreira; Lucielli Savegnago; Gelson Perin

Publisher: John Wiley and Sons
Year: 2011
Weight: 29 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201114090

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✦ Synopsis

Abstract

Alumina‐supported KF‐promoted hydrothiolation of 1,3‐butadiynes in PEG‐400 or glycerol efficiently affords thiobutenynes with clear to complete (Z)‐selectivity.

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