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ChemInform Abstract: Synthesis of Vinyl Spirolactones and Lactams by Sequential Cross-Coupling Metathesis, [2 + 2] Photocycloaddition and Cyclobutane Ring-Opening.

✍ Scribed by Sophie Faure; Sylvie Piva-Le Blanc; Olivier Piva

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199945090

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Unsaturated oxoesters and amides have been submitted to cross-coupling metathesis with trimethylallylsilane using Grubbs' catalyst. The resulting allylsilanes underwent, under irradiation, intramolecular [2+2] photocycloaddition leading to trimethylsilylmethylcyclobutanes. By treatment with an appro

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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