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ChemInform Abstract: Synthesis of Thromboxane A2 Models from Glucose. Part 2. Epoxidation Studies of Hex-2-enopyranosides.

✍ Scribed by A. FERNANDEZ CIRELLI; O. MORADEI; J. THIEM

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Synthesis of Thromboxane A2 Models from
Synthesis of Thromboxane A2 Models from Glucose. II. Epoxidation Studies of Hex-2-enopyranosides
✍ Cirelli, Alicia FernΓ‘ndez ;Moradei, Oscar ;Thiem, Joachim πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 458 KB

## Abstract The synthesis of halohydrin 7, a potential precursor of the heterocyclic moiety of thromboxane A~2~ (TXA~2~) is described. Claisen‐Meerwein‐Eschenmoser rearrangement of hex‐3‐enopyranosides 4 and 8 yields the branched olefin sugars 5 and 9. Epoxidation studies with perbenzimidic acid (P