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ChemInform Abstract: Synthesis of the Racemates of the β-Carboline Alkaloid Chrysotricine and Its Diastereomer.

✍ Scribed by Siavosh Mahboobi; Markus Koller; Dieter Schollmeyer

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200028212

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## Abstract For Abstract see ChemInform Abstract in Full Text.

β-Carboline alkaloids 9 [1]. Total synth

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## Abstract The first total synthesis of the β‐carboline alkaloids arenarine A **(1)** and arenarine B **(2)** is described. Methanolysis of the α‐bromoketone **9** gives **1** in good yield. Alternatively **1** can be obtained from the diazoketone **11** with boron trifluoride/methanol in poor yie