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ChemInform Abstract: Synthesis of the C38—C44 Segment of Altohyrtin A — With an Addendum on the Preparation of 8-Oxabicyclo[3.2.1]oct-6-en-3-one.

✍ Scribed by H. Kim; H. M. R. Hoffmann


Publisher
John Wiley and Sons
Year
2001
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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✍ Angel M. Montaña; Pedro M. Grima; Francisca García 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 66 KB 👁 2 views

The total assignment of the 1 H and 13 C NMR spectra of 24 cis-endo and 15 cis-exo diastereoisomers of C-1-substituted 2,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one derivatives was deduced from the concerted application of DEPT, COSY, HETCOR, HMBC, HMQC and PS-NOESY experiments. The relative stereo