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ChemInform Abstract: Synthesis of Substituted Acetylenic Epoxides Followed by Indium-Catalyzed Rearrangement to 2,3,5-Trisubstituted Furans.

โœ Scribed by Jun Yong Kang; Brian T. Connell


Publisher
John Wiley and Sons
Year
2011
Weight
37 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: An Epoxide Rearrang
โœ David M. Hodgson; Christopher R. Maxwell; Ian R. Matthews ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

An Epoxide Rearrangement -Radical Rearrangement Approach to 6-Substituted 2-Azabicyclo[2.2.1]-5-heptenes: Synthesis of an Epibatidine Analogue. -Base-promoted isomerization of the epoxide (I) provides the azanortricyclanol (II). The latter can be readily converted to the derivatives (V) as precurso