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ChemInform Abstract: Synthesis of Six-Membered Silaheterocycles by the Ring Enlargement of 1,1-Diphenyl-1-silacyclopent-3-ene.

✍ Scribed by Gyoergy Keglevich; Monika Trecska; Kalman Ujszaszy; Krisztina Ludanyi; Aron Szoellosy; Laszlo Toke; Serge Mignani


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthesis of six-membered silaheterocycl
✍ GyΓΆrgy Keglevich; MΓ³nika Trecska; KΓ‘lmΓ‘n ÚjszΓ‘szy; Krisztina LudΓ‘nyi; Áron SzΓΆll πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 168 KB πŸ‘ 1 views

Silabicyclo[3.1.0] hexane 2 obtained from silacyclopent-3-ene 1 by dichlorocarbene addition is useful in the synthesis of ring-expanded products, such as silacyclohexa-2,4-diene 3 and 5-alkoxysilacyclohex-3-enes 5. Catalytic hydrogenation of compound 3 affords silacyclohexane 4. The new heterocycle