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ChemInform Abstract: Synthesis of Pyrido[2,3-d]pyrimidines via Palladium-Catalyzed Coupling Reaction Followed by Electrocyclic Reaction.

✍ Scribed by Kee Yoon Rho; Joong Hyup Kim; Sung Hoon Kim; Cheol Min Yoon

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199917157

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✦ Synopsis

Synthesis of

Pyrido[2,

pyrimidines via Palladium-Catalyzed Coupling Reaction Followed by Electrocyclic Reaction.

-An efficient synthetic route to the title pyridopyrimidines [cf.

(VI), (VIII)/(IX), (XI)/(XII)] via Pd-catalyzed coupling of easily achieved 5-iodo-6aminomethyleneaminouracil (IV) with electron-rich as well as electron-deficient olefins is accomplished. -(RHO,

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