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ChemInform Abstract: Synthesis of Pseudo-Sugars Based on Desymmetrization of Dienylsilanes.

โœ Scribed by R. ANGELAUD; Y. LANDAIS

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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Carbohydrates to Carbocycles: An Expedient Synthesis of Pseudo-Sugars. -Key step in the synthesis of the title compounds, e.g. (VII), is the Claisen rearrangement reaction of the sugar derivative (III) to give the multifunctionalized carbocycle (IV), which is the starting material for the preparati