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ChemInform Abstract: Synthesis of Phosphorylated Sulfoximines and Sulfinamides and Their Application as Ligands in Asymmetric Metal Catalysis.

✍ Scribed by Eduard B. Benetskiy; Carsten Bolm

Publisher
John Wiley and Sons
Year
2011
Weight
41 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Several sulfoximine‐ and sulfinamide‐based phosphorusamides are prepared from inexpensive and easily available educts.

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Synthesis of Thiazoline–Oxazoline Ligand
Synthesis of Thiazoline–Oxazoline Ligands and Their Application in Asymmetric Catalysis
✍ Seán C. McKeon; Helge Müller-Bunz; Patrick J. Guiry 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 455 KB 👁 1 views

## Abstract A series of novel ligands incorporating oxazoline and thiazoline units were synthesized in high yield by employing a convergent route, in which the key step is a microwave‐assisted palladium‐catalyzed aryl amination. The new ligands were tested in the zinc‐catalyzed Friedel–Crafts alkyl