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ChemInform Abstract: Synthesis of Peptide Isocyanates and Isothiocyanates.

✍ Scribed by J. S. NOWICK; D. L. HOLMES; G. NORONHA; E. M. SMITH; T. M. NGUYEN; S.-L. HUANG

Book ID
112038059
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Oxidation of Isothiocyanates to Isocyanates Using Dimethyldioxirane; Relevance to Biological Activity of Isothiocyanates. -Oxidation of both alkyl and aryl isothiocyanates with dimethyldioxirane affords efficiently the corresponding isocyanates (II), which are trapped with iPrNH 2 to furnish the ur