ChemInform Abstract: Synthesis of Oxorhenium(V) Complexes Derived from 7α-Functionalized Testosterone: First Rhenium-Containing Testosterone Derivatives

Synthesis of Oxorhenium(V) Complexes Der

Synthesis of Oxorhenium(V) Complexes Derived from 7α-Functionalized Testosterone: First Rhenium-Containing Testosterone Derivatives

✍ Frank Wüst; Dieter Scheller; Hartmut Spies; Bernd Johannsen 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 404 KB 👁 1 views

In an effort to assist in the preparation of metal-containing ligands for the androgen receptor, we have synthesized the first oxorhenium(V) complexes containing a pendant testosterone moiety. The key step in the synthesis involves the copper-catalysed, α-selective 1,6-Michael addition of a 4penteny