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ChemInform Abstract: Synthesis of N,N′-Dialkylmethylenebis(nitramines) from N-Alkylsulfamates.

✍ Scribed by V. A. Tartakovsky; A. S. Ermakov; N. V. Sigai; O. N. Varfolomeeva

Publisher
John Wiley and Sons
Year
2000
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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The Reaction of Nitramines and Their N-Trimethylsilyl Derivatives with N,N-Bis(trimethylsilyloxy)enamines. -Trimethylsilylated alkylnitramine (I) reacts with N,N-bis(trimethylsilyloxy)aminopropene (II) as N-centered nucleophile to afford selectively the trimethylsilylated oxime (III) which on hydro