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ChemInform Abstract: Synthesis of New 1,8-Bridged Tricyclic Quinolones by a Novel Intramolecular Arylation of N-1 Tethered Malonamides.

✍ Scribed by D. BARRETT; H. TSUTSUMI; T. KINOSHITA; M. MURATA; K. SAKANE

Book ID: 112026997
Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199605173

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## Abstract DBU‐promoted alkylation of cyclic α‐nitroketones (I) with o‐bromobenzyl halides, e.g. (II), (V) or (VIII), followed by Pd‐catalyzed intramolecular C‐arylation provides an efficient access towards benzo‐fused bicyclo[n.3.1]alkane derivatives (III), (VI) and (IX), respectively.