ChemInform Abstract: Synthesis of Ligands Related to the Vibrio cholerae O-Specific Antigen. Part 6. Synthesis of the 2-Deoxy Analogue of the Methyl α- Glycoside of the Monosaccharide Repeating Unit of the O-Polysaccharide of Vibrio cholerae O:1.
✍ Scribed by Y. OGAWA; P. LEI; P. KOVAC
- Book ID
- 112029378
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Treatment of methyl Ot-D-perosaminide (1) with y-butyrolactone gave the 2'-deoxy analogue of methyl 4,6-dideoxy-4-(3-deoxy-L-glycero-tetronamido)-a-D-mannopyranoside (13), the methyl a-glycoside of the intracatenary monosaccharide repeating unit of the O-polysaccharide of Vibrio cholerae O:1. The an
Methyl 4-azido-4,6-dideoxy-3-O-benzyl-ct-D-mannopyranoside and its analogous 3-O-(4methoxybenzyl) derivative were methylated and the 2-O-methyl derivatives formed were convetted into methyl 4-amino-4,6-dideoxy-2-O-methyl-a-o-mannopyranoside. Reaction of the latter with 3-deoxy-L-glycero-tetronolacto