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ChemInform Abstract: Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C—C and C—N Coupling Between Oximines and Alkynes.

✍ Scribed by Xingping Zhang; Dan Chen; Miao Zhao; Jing Zhao; Aiqun Jia; Xingwei Li

Publisher
John Wiley and Sons
Year
2011
Weight
33 KB
Volume
42
Category
Article
ISSN
0931-7597

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Synthesis of Isoquinolines via Rhodium(I
Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative CC and CN Coupling between Oximines and Alkynes
✍ Xingping Zhang; Dan Chen; Miao Zhao; Jing Zhao; Aiqun Jia; Xingwei Li 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 193 KB

## Abstract Isoquinolines have been synthesized from the redox‐neutral dehydrative CN and CC cross‐coupling between oximines and alkynes using a catalytic amount of (pentamethylcyclopentadiene)rhodium dichloride dimer {[RhCp\*Cl~2~]~2~} and cesium acetate (CsOAc), a process that involves __ortho_