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ChemInform Abstract: Synthesis of Highly Substituted Cyclobutane Fused-Ring Systems from N-Vinyl β-Lactams Through a One-Pot Domino Process.

✍ Scribed by Lawrence L. W. Cheung; Andrei K. Yudin

Publisher
John Wiley and Sons
Year
2010
Weight
99 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A domino [3.3]‐rearrangement/6π‐electrocyclization process furnishes highly substituted pyridine‐fused cyclobutane derivatives and thus provides an promising method for preparation of fused heterocycles.

📜 SIMILAR VOLUMES

Synthesis of Highly Substituted Cyclobut
Synthesis of Highly Substituted Cyclobutane Fused-Ring Systems from N-Vinyl β-Lactams through a One-Pot Domino Process
✍ Lawrence L. W. Cheung; Andrei K. Yudin 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 355 KB

## Abstract In this contribution, aminocyclobutanes, as well as eight‐membered enamide rings, have been made from __N__‐vinyl β‐lactams. The eight‐membered products have been formed by a [3,3]‐sigmatropic rearrangement, whereas the aminocyclobutanes have been derived from a domino [3,3]‐rearrangeme