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ChemInform Abstract: Synthesis of Highly Functionalized Cyclohexenone Rings: Rhodium-Catalyzed 1,3-Acyloxy Migration and Subsequent [5 + 1] Cycloaddition.

✍ Scribed by Dongxu Shu; Xiaoxun Li; Min Zhang; Patrick J. Robichaux; Weiping Tang

Publisher: John Wiley and Sons
Year: 2011
Weight: 38 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201120057

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✦ Synopsis

Abstract

The title reaction of various cyclopropanes in the presence of carbon monoxide results in stereoselective formation of cyclohexenone derivatives.

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