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ChemInform Abstract: Synthesis of Functionalized Tricyclo(5.3.1.02,6)undecadienones.

โœ Scribed by V. SINGH; B. JAGADISH

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Synthesis of Functionalized Tricyclo(5.3.1.02,6)

undecadienones.

-A facile synthesis of the functionalized tricycloundecadienones (VII) and (VIII) via acid catalyzed rearrangements of endo anellated bicyclooctenones is described.

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ChemInform Abstract: Enantioselective Sy
ChemInform Abstract: Enantioselective Synthesis of 4-Aminocyclopent-2-ene-1-one from Tricyclo[5.2.1.02,6]decenyl Enaminones.
โœ N. G. RAMESH; A. J. H. KLUNDER; B. ZWANENBURG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 39 KB ๐Ÿ‘ 1 views

Enantioselective Synthesis of 4-Aminocyclopent-2-ene-1-one from Tricyclo[5.2.1.0 2,6 ]decenyl Enaminones. -The enantioselective synthesis of hitherto unknown 4-aminocyclopent-2-en-1-one (VI) involves reaction of enamine (III) with lithium liquid ammonia which not only results in reduction of the en