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ChemInform Abstract: Synthesis of Five-Membered 2-Heteroaryl 2-Heteroaromatic Carboxylates and Attempted Cyclization to Bisheteroaryl[2,3-b:3′,2′-d]pyran-2-one.

✍ Scribed by C. K. LEE; J. S. YU; S. H. KIM


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Synthesis of pyran (and furan)-3-yl Methanols by Oxygenative Radical Cyclization. -A general one-step method for the synthesis of title compounds including carbohydrate derivatives is given using two effective catalytic systems, Bu 3 SnH/AIBN/O 2 and Co(salen)/NaBH 4 /O 2 . Competition from o