ChemInform Abstract: Synthesis of exo-Methylenedifluorocyclopentanes (V), (IX) as Precursors of Fluorinated Carbasugars by 5-exo-Dig Radical Cyclization.
β Scribed by Gaelle Fourriere; Eric Leclerc; Jean-Charles Quirion; Xavier Pannecoucke
- Book ID
- 112046614
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 34 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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A Novel Entry to 5a-Carba-hexopyranoses from Carbohydrates Based on a 6-exo-dig Radical Cyclization: Synthesis of 5a-CarbaΞ²-D-mannopyranose Pentaacetate. -Mannose-derived diacetonide (VI) undergoes a 6-exo-dig radical cyclization to give highly functionalized cyclohexanes which are correlated with