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ChemInform Abstract: Synthesis of Enantiomerically Pure Mono-, Di-, and Trisubstituted 2- Sulfinylbuta-1,3-dienes, via β-Hydroxy Selenides.

✍ Scribed by P. GOSSELIN; E. BONFAND; C. MAIGNAN

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of Enantiomerically Pure Mono-, Di-, and Trisubstituted 2-Sulfinylbuta-1,3-dienes, via β-Hydroxy Selenides.

-While deoxygenation of the epoxide (III) results in the exclusive formation of the sulfide (IV), elimination of the hydroxy selenides ( VI) according to the methods of Krief and Reich gives the desired optically active sulfinylbutadienes (VII), which are potentially useful in terpenoid synthesis. -(GOSSELIN, P.; BONFAND,

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