ChemInform Abstract: Synthesis of Enantiomerically Pure D- and L-Armentomycin and Its Difluoro Analogues from Aspartic Acid.

✍ Scribed by D. WINKLER; K. BURGER

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 28 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199722206

✦ Synopsis

Synthesis of Enantiomerically Pure D-and L-Armentomycin and Its Difluoro Analogues from Aspartic Acid.

-The biologically active title compound (V) and its difluoro analogue ( VII) are prepared without racemization via the hexafluoroacetone-protected intermediate (III). -