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ChemInform Abstract: Synthesis of Enantiomerically Pure (2R,5S)- (XVII) and (2R,5R)-5- Hydroxypipecolic Acid (XVIII) from Glycinate Schiff Bases (III).

✍ Scribed by S. HOARAU; J. L. FAUCHERE; L. PAPPALARDO; M. L. ROUMESTANT; P. VIALLEFONT


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (2S*,4
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Synthesis of (2S\*,4R\*,5S\*)-Piperidinetricarboxylic Acid, a Non-Proteinogenic Amino Acid Isolated from Clitocybe Acromelalga. -The title compound (IX) is synthesized from the pyridine triester (VI) by stepwise hydrogenation of the pyridine ring with intermediate cis-trans isomerization. -(HASHIMO