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ChemInform Abstract: Synthesis of Cytotoxic Ferrocenyl Flavones via a Ferricenium-Mediated 1,6-Oxidative Cyclization.

✍ Scribed by Jean-Philippe Monserrat; Guy G. Chabot; Louis Hamon; Lionel Quentin; Daniel Scherman; Gerard Jaouen; Elizabeth A. Hillard

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201047177

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✦ Synopsis

Abstract

The oxidation of the ferrocenyl group of 2′‐hydroxyferrocenyl chalcones (II) activates the β‐position of the unsaturated ketone to nucleophilic attack to yield the first examples of ferrocenyl flavones (III).

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