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ChemInform Abstract: Synthesis of Cyclic β-Silylenones via Oxidative Rearrangement of Tertiary α-Hydroxy Allylsilanes with PCC.

✍ Scribed by Xia Wu; Jian Lei; Zhen Lei Song

Publisher
John Wiley and Sons
Year
2011
Weight
32 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The reaction provides six‐membered cyclic β‐silylenones (II) in moderate yields, whereas the five‐membered product (IV) is achieved in excellent yield.

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