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ChemInform Abstract: Synthesis of Cleviolide and the Scobinolides.

✍ Scribed by G. J. HOLLINGWORTH; A. M. E. RICHECOEUR; J. SWEENEY

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of Cleviolide and the Scobinolides.

-The palladiumcatalyzed cross-coupling reaction of the stannylfuranone (V) and the iodopentenyne derivative (IVa) gives the natural product cleviolide (VI) from which both (Z)-and (E)-isomers of scobinolide ( VII) and (VIII) are prepared. -(HOLLINGWORTH, G.

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