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ChemInform Abstract: Synthesis of Carboxylated Pyrrolidine Derivatives via 1,3-Dipolar Cycloadditions of Homochiral Double-Stabilized E-Azomethine Ylides.

โœ Scribed by L. M. HARWOOD; I. A. LILLEY


Book ID
112024609
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Diastereoselective synthesis of pyrrolid
โœ K. Karthikeyan; R. Senthil Kumar; D. Muralidharan; P.T. Perumal ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 691 KB

1,3-Dipolar cycloaddition of D-glucose-derived azomethine ylides for the synthesis of chiral pyrrolidines accompanied an unexpected 1,2-elimination in the furanose moiety of the products. The C3 0 alkoxy/ hydroxy group of the furanose moiety was invariably eliminated under the reaction conditions. A