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ChemInform Abstract: Synthesis of Bridgehead-Functionalized Bicyclo[3.2.1]octanes via Intramolecular Titanium- and Tributylstannane-Induced Pinacol Coupling.

✍ Scribed by A. EGGER; J. HUNZIKER; G. RIHS; C. LEUMANN

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Benzo-
ChemInform Abstract: Synthesis of Benzo- and Naphtho-Fused Bicyclo[n.3.1]alkane Frameworks with a Bridgehead Nitrogen Function by Palladium-Catalyzed Intramolecular α′-Arylation of α-Nitroketones.
✍ Giorgio Giorgi; Swarupananda Maiti; Pilar Lopez-Alvarado; J. Carlos Menendez 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 38 KB

## Abstract DBU‐promoted alkylation of cyclic α‐nitroketones (I) with o‐bromobenzyl halides, e.g. (II), (V) or (VIII), followed by Pd‐catalyzed intramolecular C‐arylation provides an efficient access towards benzo‐fused bicyclo[n.3.1]alkane derivatives (III), (VI) and (IX), respectively.