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ChemInform Abstract: Synthesis of Bicyclo(3.3.1)nonanes via Manganese(III) Mediated Radical Cyclization of Olefinic β-Keto Esters.

✍ Scribed by J. D. WHITE; S. C. JEFFREY


Book ID
112024962
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
27
Category
Article
ISSN
0931-7597

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Manganese (III) acetate and lewis acid m
✍ Maria I. Colombo; Sandra Signorella; Mirta P.Mischne; Manuel Gonzalez-Sierra; Ed 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 319 KB

'-trimethylcyclohex-2'-enyl and l'-enyl) pentanoatee &and g were submitted to both: Lewis acid (tin (IV) tetrachloride) and free radical (manganese (III) acetate) cyclization conditions. The structures of the different products are discussed in terms of the reaction mechanisms. Lewis acid and photo