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ChemInform Abstract: Synthesis of Asymmetrical Methyl-Branched Chiral Ketones from the Corresponding Homologous Wax Esters. A New Synthesis of the Insect Pheromone Lardolure and of 9-Norlardolure.

✍ Scribed by M. MORR; C. PROPPE; V. WRAY

Book ID
112027737
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Synthesis of asymmetrical methyl-branche
Synthesis of asymmetrical methyl-branched chiral ketones from the corresponding homologous wax esters. A new synthesis of the insect pheromone lardolure and of 9-norlardolure
✍ Morr, Michael ;Proppe, Christiane ;Wray, Victor 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB

## Abstract The insect pheromone (2__R__4__R__6__R__,8__R__)‐4,6,8‐trimethyl‐2‐undecyl formate (lardolure, 7c) and (2__R__,4__R__,6__R__,8__R__)‐4,6,8‐trimethyl‐2‐decyl formate (9‐norlardolure, 7b) have been synthesized from the corresponding homologous chiral methyl‐branched esters 1b and 1c, whic