ChemInform Abstract: Synthesis of an Epoxide- and Carbonate-Containing 6-/10-Membered Bicyclodienediyne Analogue of the Neocarzinostatin Chromophore.
β Scribed by F. FERRI; R. BRUECKNER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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An Epoxide Rearrangement -Radical Rearrangement Approach to 6-Substituted 2-Azabicyclo[2.2.1]-5-heptenes: Synthesis of an Epibatidine Analogue. -Base-promoted isomerization of the epoxide (I) provides the azanortricyclanol (II). The latter can be readily converted to the derivatives (V) as precurso
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