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ChemInform Abstract: Synthesis of Alkynyl-Substituted Pyrrolidin-1-yloxyl Radicals from 1- Pyrroline N-Oxide Nitrones and Alkynylmagnesium Bromides.

✍ Scribed by N. M. BARACZ; O. H. HANKOVSZKY; C. P. SAR; G. JERKOVICH; K. HIDEG


Book ID
112034354
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (R)- a
✍ S.-I. MURAHASHI; H. OHTAKE; Y. IMADA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 36 KB πŸ‘ 1 views

Synthesis of (R)-and (S)-3-(tert-Butyldimethylsilyloxy)-1-pyrroline N-Oxides -Chiral Nitrones for Synthesis of Biologically Active Pyrrolidine Derivative, Geissman-Waiss Lactone. -Tungstatemediated oxidation of the chiral Tbs-protected 3-hydroxypyrrolidines (II) provides the required nitrones (III)