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ChemInform Abstract: Synthesis of Alkyl Hydrogen (1-Aminoalkyl)phosphonates.

โœ Scribed by Radii M. Khomutov; Elena N. Khurs; Tatyana I. Osipova

Publisher
John Wiley and Sons
Year
2011
Weight
25 KB
Volume
42
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

Addition of hypophosphorous acid to aldoximes (I) affords aminoalkyl phosphinic acids (II) which on treatment with bromine in the appropriate alcohol give aminoalkyl phosphonates (IV).

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## Abstract The transformation of substrates (I) succeeds without any catalyst to give the synthetically important novel title compounds (III) in moderate to good yield.